Easy Tutorial
For Competitive Exams

The half cell reaction, with its standard reduction potentials are:
(i) Pb2++ 2e → Pb (E° = –0.13 V)
(ii) Ag++ e → Ag (E° = +0.80 V)
Which ofthe following reactions will occur?

Pb2++ 2Ag → 2Ag+ + Pb
Pb2++ H2 → 2H+ + Pb
2H++ 2Ag → 2Ag+ + H2
2Ag++ Pb → Pb+ + 2Ag
Additional Questions

Given Eo
Fe3+/Fe
= –0.036 V, Eo
Fe2+/Fe
= –0.439 V.

The value of standard electrode potential for the change,

Fe3+(aq) + e → Fe2+ will be

Answer

Hydrogen gas is not liberated when the following metal is added to dil. HCl.

Answer

Electrolysis of dilute aqueous NaCl solution was carried out by passing 10 milliampere current. The time required to liberate 0.01 mol of H2 gas at the cathode is (1 Faraday = 96500 C mol–1)

Answer

Given Eo
Cr3+/Cr
= –0.72 V, Eo
Fe2+/Fe
= –0.42,

the potential for the cell Cr / Cr3+ (0.1 M) || Fe2+ (0.01 M) | Fe is

Answer

ElectrolyteKClKNO3 HClNaOAcNaCl
Λ(S cm2mol–1)149.9145426.291126.5

Calculate Λ
HoAc
using appropriate molar conductances of the electrolytes listed above at infinite dilution in H2O at 25°C

Answer

The equivalent conductances of two strong electrolytes at infinite dilution in H2O (where ions move freely through a solution) at 25°C are given below:

Λo
CH3COONa
= 91.0 S cm2 / equiv

Λo
CHCl
= 426.2 S cm2 / equiv

What additional information/quantity one needs to calculate Λ° of an aqueous solution of acetic acid?

Answer

In a cell that utilizes the reaction

Zn(s) + 2H+ (aq) → Zn2+ (aq) + H2(g)

addition of H2SO4 to cathode compartment will

Answer

For the reduction of silver ions with copper metal the standard cell potential was found to be +0.46 V at 25°C. The value of standard Gibbs energy, ΔG° will be (F = 96500 C mol–1)

Answer

In the electrolysis of acidulated water, it is desired to obtain 1.12 cc of hydrogen per second under S.T.P. conditions. The current to be passed is

Answer

The one which decreases with dilution is

Answer
Share with Friends
Privacy Copyright Contact Us