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During the kinetic study of the reaction, 2A + B → C + D, following results were obtained:

Run[A]/mol L–1[B]/mol L–1Initial rate of formation of D/mol L–1 min–1
I0.10.16.0 × 10–3
II0.30.27.2 × 10–2
III0.30.42.88 × 10–1
IV0.40.12.40 × 10–2

Based on the above data which one of the following is correct?

rate = k[A]2 [B]2
rate = k[A] [B]2
rate = k[A]2 [B]
rate = k[A] [B]
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